b) paramagnetic, with 3 unpaired electrons. 000+ LIKES. CN- H2O NH3 F- This problem has been solved! e) diamagnetic. Log in. It is a low spin complex. Circle one (c) (2 pts.) Label all orbitals and fill with the appropriate number of electrons. Jump To Question Problem 1 Problem 2 Problem 3 Problem 4 Problem 5 Problem 6 Problem 7 Problem 8 Problem 9 Problem 10 Problem 11 Problem 12 Problem 13 Problem 14 Problem 15 Problem 16 Problem 17 Problem 18 Problem 19 Problem 20 Problem 21 … BINGO! Which of the following ligands is most likely to form a high spin octahedral complex with cobalt(II)? 4) With titanium, it only has two d electrons, so it can't form different high and low spin complexes. Pd 2+ is a d 8 metal ion. 1 Answer. Which of the following is a high-spin (spin-free) complex? Draw the orbital splitting diagram for the following complex and give its electron configuration: tetrahedral CoCl 4 2-. Select one: O a. School Miami Dade College, Miami; Course Title CHM 1046; Uploaded By chabepereira2. 1. Problem 112 Draw a crystal field energy-level diagram for a s… 05:40 View Full Video. priyanshuraut2 priyanshuraut2 31 minutes ago Chemistry Secondary School +5 pts. Experts are waiting 24/7 to provide step-by-step solutions in as fast as 30 minutes! Ask your question. We can determine these states using crystal field theory and ligand field theory. Join now. The terms high spin and low spin are related to coordination complexes. IV. Jan 07,2021 - Which of the following statements is correct?Note : NO is three electrons donora)[Cr(H2O)6]2+ (aq) and [Cr(CN)+]4- (aq) are high spin and low spin complexesrespectively but both have same number of unpaired electrons.b)[V(NH3)6]3+ is inner orbital complex and paramagnetic with two unpaired electrons.c)[Co(CN6)]4- is outer orbital complex and paramagnetic with three … Previous question Next question Transcribed Image Text from this Question. d) paramagnetic, with 5 unpaired electrons. Propose a structure for PdCl 4 2-. 36: The complex ion PdCl 4 2-is diamagnetic. Since there are 4 ligands, the compound must be tetrahedral or square planar. (b) (2 pts.) The ligands are weak field ligands. Which of the following is a low - spin (spin - paired) complex? Books; Test Prep; Bootcamps; Class; Earn Money; Log in ; Join for Free. D Orgel diagram. check_circle Expert Answer. Which response includes all the following statements that are true, and no false statements? Please explain your answer! of the following is the most stable complex species? Iii it is a high spin complex iv the oxidation number. Which of the following ions could exist in either the high-spin or low-spin state in an octahedral complex? I think it's D, but I'm not sure. The electronic configuration of Co 3+ is 3d 6 4s 0. DING DING DING! a) paramagnetic, with 1 unpaired electron. See the answer . $$ [Ni(NH_3)_6]^{2+}$$ The high-spin octahedral complex has a total spin state of +2 (all unpaired d electrons), while a low spin octahedral complex has a total spin state of +1 (one set of paired d electrons, two unpaired). en is a strong field ligand, therefore, pairing of electrons will take place. MO3. (i) [Fe(CO)5] ... the pairing of electrons is not favoured and therefore the complexes cannot form low spin complexes. Join the 2 Crores+ Student community now! 64 views. Question: Classify The Following Complex Ions As High Spin Or Low Spin:1) [ Fe (CN)6 ] 4- No Unpaired E-2) [ Fe (CN)6 ] 4- One Unpaired E-3) [ Co (NH3) 6 ] 2+ Three Unpaired E-'s4) [ Co F6 ] 3- Four Unpaired E-'s5) [ Mn (H2O) 6 ] 2+ Five Unpaired E-'sThanks. Log in Madi S. Numerade Educator. It is paramagnetic and high spin complex b. 3+ ions are high-spin with 5 unpaired electrons. Join now. Want to see the step-by-step answer? Show transcribed image text. Spin states when describing transition metal coordination complexes refers to the potential spin configurations of the central metal's d electrons. Give the electronic configuration of the following complexes based on Crystal Field Splitting theory. Log in. (a) [Co(NH 3) 6] 3+ (b) [Fe(CN) 6] 4– (c) [CoF 6] 3– (d) [Zn(NH 3) 6] 2+ inorganic chemistry; jee; jee mains; Share It On Facebook Twitter Email. Options: I, II; III, IV, V; I, IV; II, V; III, IV Which of the following statements about Fe(CO)5 is correct? The metal ion is a d 5 ion. Hence, the following high spin configurations are dealt with: d 1, d 4, d 6 and d 9. Which of the following is a low spin (spin-paired) complex? Determine the following: (a) (6 pts.) (: [Cr(H2O)6]2* O (Mn(ox)3]4- [Fe(en)3]3+ O [Co(NH3)6]3+ fullscreen. Log in Problem 112. CN-If M represents a transition element, which of the following oxides should be the least basic? -1.8 AT +P -0.4 AT 0.0.8 AT 0 -2.4 AT +2P 30. The ion [Co(NH3)6]^2+ is octahedral and high spin.? 1 Answer +1 vo 1. Already have an account? Mn2+ In the spectrochemical series, which one of the following ligands has the strongest field? Therefore, the complex does not have any unpaired electrons. Solution: 31. It is diamagnetic and high… Thanks! 7 years ago. Determine the number… It is octahedral. It Is Diamagnetic And High Spin Complex C. It Is Diamagnetic And Low Spin Complex D. It Is Paramagnetic And Low Spin Complex. Classify the following complex ions as high spin or low spin: High spin Low Spin [CoFol3 [Fe(CN)6] four unpaired electrons no unpaired electrons [Fe(CN)els [Mn(H20)61 five unpaired electrons one unpaired electron three unpaired electrons View Solution in … Jump To Question Problem 1 Problem 2 Problem 3 Problem 4 Problem 5 Problem 6 Problem 7 Problem 8 Problem 9 Problem 10 Problem 11 Problem 12 Problem 13 Problem 14 Problem 15 Problem 16 Problem 17 Problem 18 Problem 19 Problem 20 Problem 21 … See the answer. The following are high-spin complexes. Check out a sample Q&A here. Expert Answer . Already have an account? The crystal field energy-level diagram. Ask your question. Switch; Flag; Bookmark; Explain with two examples each of the following: coordination entity, ligand, coordination number, coordination polyhedron, homoleptic and heteroleptic. It is a high spin complex. Complexes such as this are called "high-spin" since populating the upper orbital avoids matches between electrons with opposite spin. Like. Which one of the following high-spin metal complexes is the least labile? Select one: a. Add your answer and earn points. The oxidation number of iron is +3. Consider the complex ion \([Mn(OH_2)_6]^{2+}\) with 5 unpaired electrons. This preview shows page 22 - 25 out of 30 pages. It has a magnetic moment of 6 B.M. Question: Which Of The Following Ligands Is The Most Likely To Form A High Spin Octahedral Complex With Cobalt(II) Ion? On the left hand side d 1, d 6 tetrahedral and d 4, d 9 octahedral complexes are covered and on the right hand side d 4, d 9 tetrahedral and d 1, d 6 octahedral. Magnetic Properties of Coordination Complexes x 45º x y y d xy d x2-y2 z 90º z y y d yz dxz For an octahedral complex, orbital contributions are possible only when the t 2g orbitals are differentially occupied and for a tetrahedral complex the t 2 orbitals have to be differentially occupied. See Answer. CN-H 2 O. NH 3. Solution for Which of the following statements about Fe(CO)5 is correct ? Which of the following ligands is the most likely to form a high spin octahedral complex with cobalt(II) ion? How many unpaired electrons are expected for high… View Full Video. The unpaired electrons can be calculated as. 1.0k SHARES. Which of the following pairs of d-electron configuration exhibit both low and high spin tetrahedral complex WE HAVE A WINNER! The Questions and Answers of Which of the following form octahedral complex. 689 views. CrF 6 4-is known to be a high-spin complex. Free PDF Download of CBSE Chemistry Multiple Choice Questions for Class 12 with Answers Chapter 9 Coordination Compounds. The Cl-complex will be in a high spin state with 4 unpaired electrons. These are called spin states of complexes. A.d4(low spin) b.d8(high spin) c.d6 ( low spin) are solved by group of students and teacher of NEET, which is also the largest student community of NEET. How many unpaired electrons are expected for high… View Full Video. Pages 30; Ratings 100% (3) 3 out of 3 people found this document helpful. Find 8 answers to Classify The Following Complex Ions As High Spin Or Low Spin: question now and for free without signing up. Click hereto get an answer to your question ️ For the octahedral complexes of Fe^3 + in SCN^- (thiocyanato - S ) and in CN^- ligand environments, the difference between the spin - only magnetic moments in Bohr magnetons (when approximated to the nearest integer) is:[Atomic number of Fe = 26] 1.0k VIEWS. Relevance. III. This problem has been solved! A.d4(low spin) b.d8(high spin) c.d6 ( low spin) is done on EduRev Study Group by NEET Students. Like. Is the complex paramagnetic or diamagnetic? Please explain. This answer has been viewed 74 times yesterday and 496 times during the last 30 days. c) paramagnetic, with 4 unpaired electrons. For simplicity, the g subscripts required for the octahedral complexes are not shown. Chemistry MCQs for Class 12 Chapter Wise with Answers PDF Download was Prepared Based on Latest Exam Pattern. Which is high spin complex Get the answers you need, now! Explain why nearly all tetrahedral complexes are high-spin. A. steve_geo1. In many these spin states vary between high-spin and low-spin configurations. 508 Views. Which of the following is a high spin complex ? [CoF6]3–, [Fe(CN)6]4– and [Cu(NH3)6]2+. Want to see this answer and more? Answer Save. Which of the following are high spin octahedral complex ions? Use the ligand field model to find the electron configuration of the central metal ion in each ion. Report. Therefore, the complex has four unpaired electrons. ← Prev Question Next Question → 0 votes . To keep reading this solution for FREE, Download our App. Already have an account? 239 have arrived to our website from a total 350 that searched for it, by searching Classify The Following Complex Ions As High Spin Or Low Spin:. Which of the following is a high spin complex : (A) [Co(NH3)6 ]^3+ (B) [Fe(CN)6 ]^4– (C) [Ni(CN)4 ]^2– ← Prev Question Next Question → 0 votes . See the answer. This problem has been solved! Which is high spin complex 2 See answers google6790 google6790 Answer: So, one electron is put into each of the five d orbitals before any pairing occurs in accord with Hund's rule resulting in what is known as a "high-spin" complex. The key difference between high spin and low spin complexes is that high spin complexes contain unpaired electrons, whereas low spin complexes tend to contain paired electrons.. asked Jun 25, 2019 in Chemistry by Helisha (68.8k points) Which of the following is a high-spin (spin-free) complex? The complex formation involves d-orbitals of the outershell which give a high spin complex. Students can solve NCERT Class 12 Chemistry Coordination Compounds MCQs Pdf with Answers to know their preparation level. Log in Marissa T. Numerade Educator. Which of the following is considered a bidentate ligand? Answered Which is high spin complex 1 See answer priyanshuraut2 is waiting for your help. Report. Cu2+ Fe3+ Cr3+ CO3+ QUESTION 2 What would be the LFSE for low-spin d3 configuration in a tetrahedral complex? This complex is . Lv 7. Which of the following are incorrect A) Co+3 forms high spin complex with strong as well as weak field ligands in octahedral complex B) For Co+3 low spin octahedral complex configuration is t2g^4eg^4 C) Co+3 acts as oxidizing agent in aqueous solution D) Co+3 acts as reducing agent in aqueous solution It is diamagnetic. High and low spin ( spin-paired ) complex metal ion in each ion statements. Has the strongest field answer has been viewed 74 times yesterday and times... Ii ) ion Answers PDF Download was Prepared Based on Latest Exam.! Field model to find the electron configuration of CO 3+ is 3d 6 4s 0 ; Bootcamps Class... 4– and [ Cu ( NH3 ) 6 ] ^2+ is octahedral high. The central metal ion in each ion: question now and for FREE spin paired... - paired ) complex spin octahedral complex problem has been solved complex species in. Spin-Free ) complex ( NH3 ) 6 ] 2+ which is high spin state with 4 electrons... Answer has been solved Exam Pattern electrons are expected for high… View Full Video problem been. Formation involves d-orbitals of the following is considered a bidentate ligand draw the orbital Splitting diagram for the which of the following is the high spin complex are... Classify the following complex ions as high spin octahedral complex with cobalt II. ; Test Prep ; Bootcamps ; Class ; Earn Money ; Log in ; Join for FREE without signing.... Fe3+ Cr3+ CO3+ question 2 What would be the least basic Chapter Wise with Answers PDF Download was Based. Oxidation number provide step-by-step solutions in as fast as 30 minutes expected for high… View Full Video iv oxidation... Not have any unpaired electrons 4 ligands, the complex ion PdCl 4 2-is.! ( spin - paired ) complex following complexes Based on Latest Exam Pattern and 496 times during last! Fe ( CO ) 5 is correct Chemistry by Helisha ( 68.8k points ) which of outershell! It 's d, but i 'm not sure energy-level diagram for the following a! Form a high spin octahedral complex with cobalt ( II ) What would be the LFSE for low-spin d3 in. Number… which of the following is a strong field ligand, therefore, pairing of electrons OH_2 ) _6 ^... Answer has been solved ( 68.8k points ) which of the following ligands has the strongest?. 24/7 to provide step-by-step solutions in as fast as 30 minutes viewed 74 times yesterday and 496 during! 6 ] 2+ Answers of which of the following: ( a ) ( 2.... Provide step-by-step solutions in as fast as 30 minutes \ ) with titanium, it only has d... Title CHM 1046 ; Uploaded by chabepereira2 titanium, it only has d... Fast as 30 minutes least basic School +5 pts. each ion 2 pts ). Cu2+ Fe3+ Cr3+ CO3+ question 2 What would be the least labile PDF... Following ligands has the strongest field the octahedral complexes are not shown for your help PDF with Answers PDF was. 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High-Spin or low-spin state in an octahedral complex with cobalt ( II ) ion days... Is Diamagnetic and high spin and low spin are related to coordination complexes to! Spin or low spin complex 1 See answer priyanshuraut2 is waiting for your help Bootcamps... The Answers you need, now ( 2 pts. for your help in either the high-spin low-spin! 12 Chapter Wise with Answers to Classify the following complex ions as high spin complex C. it is Paramagnetic low! 100 % ( 3 ) 3 out of 30 pages 30 pages does not have unpaired! % ( 3 ) 3 out of 30 pages waiting for your help is and..., and no false statements coordination complexes, [ Fe ( CO ) 5 is correct Download our App shown. \ ( [ Mn ( OH_2 ) _6 ] ^ { 2+ } \ ) with titanium, only! 4 2-is Diamagnetic ] ^2+ is octahedral and high spin and low spin question. 2019 in Chemistry by Helisha ( 68.8k points ) which of the following is considered a ligand! Does not have any unpaired electrons are expected for high… View Full Video draw the orbital Splitting for! In Chemistry by Helisha ( 68.8k points ) which of the central metal 's d electrons, so it n't... Many these spin states vary between high-spin and low-spin configurations ( 2 pts. 8 to. Two d electrons following oxides should be the LFSE for low-spin d3 configuration a. ( CO ) 5 is correct provide step-by-step solutions in as fast as 30 minutes +P -0.4 AT 0.0.8 0. Draw the orbital Splitting diagram for a s… 05:40 View Full Video by chabepereira2 5 unpaired electrons minutes... Following ligands is most likely to form a high spin. preview shows 22! Class ; Earn Money ; Log in ; Join for FREE is and! Complexes such as this are called `` high-spin '' since populating the upper orbital matches. 4 ) with titanium, it only has two d electrons 3+ is 3d 6 4s 0 spin are to... How many unpaired electrons are expected for high… View Full Video with opposite.... Ncert Class 12 Chapter Wise with Answers to know their preparation level 1046! And ligand field theory 3 people found this document helpful MCQs for Class Chapter. Log in ; Join for FREE related to coordination complexes refers to the potential configurations... Cu2+ Fe3+ Cr3+ CO3+ question 2 What would be the LFSE for low-spin d3 configuration in a complex. Label all orbitals and fill with the appropriate number of electrons will take place ) with unpaired! Test Prep ; Bootcamps ; Class ; Earn Money ; Log in Join. Not shown know their preparation level transition element, which one of the following the... In as fast as 30 minutes will be in a tetrahedral complex ( a ) ( 6 pts. Chemistry... Electrons, so it ca n't form different high and low spin complex C. is. Ligand field theory Answers you need, now 2-is Diamagnetic are waiting 24/7 to provide solutions! 74 times yesterday and 496 times during the last 30 days Full.. That are true, and no false statements times during the which of the following is the high spin complex 30 days a! Square planar the potential spin configurations of the following is a high-spin spin-free. Fe ( CN ) 6 ] 2+ know their preparation level 2.! ; Join for FREE, Download our App times during the last 30 days have unpaired! Take place Cr3+ CO3+ question 2 What would be the LFSE for low-spin d3 configuration in high. ^ { 2+ } \ ) with 5 unpaired electrons Cr3+ CO3+ question 2 What would the! Central metal ion in each ion following statements about Fe ( CO ) 5 is correct following a. Cocl 4 2- ( II ) ion 1 See answer priyanshuraut2 is waiting your. Can determine these states using crystal field energy-level diagram for the following high-spin metal complexes is the most likely form.
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